I think::
If you connect two 11.1v, 2200 mAh batts in series , it will yield 22.2v, 2200 mAh.
If you connect two 11.1 v, 2200 mAh batts in parallel, it will yield 11.1 v, 4400 mAh.
I think this is correct, but maybe some one else will chime in.
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I'm sure you can charge two batts of same v and mAh rating, but I'm not sure of the hook up. Again some help from the peanut gallery would be good.
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Yes, Deans connectors can be a pain in the butt, when new they are hard to connect and disconnect, but they are reliable. After being used for awhile, they get better.
Hope I have been helpful'
Donnie D